 成长值: 66955
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楼主应该是参考《碳酸甲乙酯反应体系的分离》这篇文章的参数进行模拟的，文章中采用的是间歇精馏。
给楼主一些参数，再算算吧！
| MEOH | Conventional | METHANOL | CH4O | | ETOH | Conventional | ETHANOL | C2H6O-2 | | DMC | Conventional | DIMETHYL-CARBONATE | C3H6O3-D3 | | EMC | Conventional | ETHYL-METHYL-CARBONATE | C4H8O3-N5 | | DEC | Conventional | DIETHYL-CARBONATE | C5H10O3-D1 |
NRTL的交互作用参数如下。
| Component i | MEOH | MEOH | MEOH | ETOH | ETOH | ETOH | DMC | DMC | EMC | | Component j | ETOH | DMC | EMC | DMC | EMC | DEC | EMC | DEC | DEC | | Temperature units | C | C | C | C | C | C | C | C | C | | Source |
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| | AIJ | 4.7119 | -1.22064 | 0.723121 | -0.881639 | 1.109 | 4.80719 | 0.656416 | 1.20124 | 0.111262 | | AJI | -2.3127 | -0.2641 | -5.01463 | -2.4461 | 0.175902 | -5.75388 | -0.480972 | -0.799305 | -0.193425 | | BIJ | -1162.2949 | 950.743 | -1.0365 | 623.862 | 0 | -1102.73 | 0.123326 | -43.5504 | 0.0803785 | | BJI | 483.8436 | -12.0905 | 1902.52 | 1002.75 | 0 | 1845.91 | -0.0325908 | 80.6666 | -0.0827029 | | CIJ | 0.3 | 0.100028 | 0.191216 | 0.5 | 0.439099 | 0.1 | 0.498405 | 0.5 | 0.469409 | | DIJ | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | | EIJ | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | | EJI | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | | FIJ | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | | FJI | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | | TLOWER | 20 | 37.82 | 64.8 | 30 | 77.89 | 25 | -59.75 | -76.05 | -84.25 | | TUPPER | 78.4 | 138 | 106 | 89.22 | 104 | 122.87 | 107.1 | 121.29 | 124.8 |
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